What is DBP in water?
Disinfection by-products (DBPs), also called trihalomethanes, are formed when chlorine and bromine interact with natural organic materials in water, such as in chlorinated drinking water and chlorine-treated swimming pools.
How are DBP formed?
Disinfection by-products (DBP) are formed when natural organic matter (NOM) in water reacts with a disinfectant, usually chlorine. DBPs are a health risk element and regulated under the Safe Drinking Water Act.
What are DBP precursors?
DBP precursors include dissolved organic carbon (DOC) and bromide. The precursor DOC contains several different forms of carbon. When DOC is fractionated, its components, hydrophobic acids and hydrophilic acids are isolated.
What are the key precursor compounds responsible for DBP formation in the presence of chlorine and ozone?
DBPs are formed by the action of oxidant-disinfectant chemicals, mainly chlorine derivatives (chlorine, hypochlorous acid, chloramines, etc.), that react with natural organic matter (NOM), mainly humic substances.
What is TTHMs?
TTHMs are a group of volatile and potentially toxic chemicals formed during water treatment with disinfectants, such as chlorine. Disinfectants are used in the treatment of water to kill disease-causing microorganisms. The most common member of TTHMs is chloroform, but others such as bromoform can be found as well.
What is the most common specific DBP chemical of concern?
In the presence of bromine, hypobromous acid is also formed. Both chlorine and bromine are in the “halogen” group of elements, and have similar chemical characteristics….USEPA Standards for DBPs.
| Table 4: USEPA Cancer Potency Factors | |
|---|---|
| Compound | Cancer Potency Factor |
| Bromoform | 0.0079 mg/kg/day |
What is the MCL for HAA5?
60 parts per billion
The USEPA and MassDEP have set an MCL for HAA5 of 60 parts per billion (ppb) or micrograms per liter (ug/L) as an annual average.
What are disinfection byproduct precursors?
DBPs are generally formed by the reaction of disinfectants such as chlorine with organic precursors present in source water; these organic precursors are mainly called natural organic matter (NOM) and NOM acts as a forerunner to DBPs. Some of the chlorination disinfection byproducts are shown in Table 1.
Is chlorite a disinfection byproduct?
Chlorite and chlorate are disinfection by-products resulting from the use of chlorine dioxide as a disinfectant and for odour/taste control in water. Chlorine dioxide is also used as a bleaching agent for cellulose, paper pulp, flour and oils and for cleaning and detanning leather.
What causes TTHMs?
Trihalomethanes are a group of chemicals that can form when organic matter in water is treated with halogen disinfectants such as chlorine. The most common of these chemicals is trichloromethane (also called chloroform), but others, such as dibromochloromethane, bromodichloromethane, or bromoform can also be found.
What is bromodichloromethane used for?
Bromodichloromethane has formerly been used as a flame retardant, and a solvent for fats and waxes and because of its high density for mineral separation. Now it is only used as a reagent or intermediate in organic chemistry.
Are DBPs carcinogenic?
World Health Organization (WHO) Research and Guideline Values for DBPs. DBCM and bromoform are not classifiable, indicating there is no evidence supporting these two compounds as carcinogens, but there is not enough research to classify them as non-carcinogenic.
DBP precursors are defined as a mixture of organic and inorganic compounds that can form DBPs under some level of disinfection. DBP formation potential (DBPFPs) experiments are designed to maximize reactions between the precursors and disinfectant (e.g., Krasner et al., 2008 ).
What does dbpfp stand for?
Water samples from W/WWTPs across the USA were collected and DBP formation potentials (DBPFPs) in the presence of free chlorine and chloramine were obtained for trihalomethane (THM), haloacetic acid (HAA), haloacetonitrile (HAN), and N-nitrosodimethylamine (NDMA).
What are disinfection by-products (DBPs)?
Formation of regulated and non-regulated disinfection by-products (DBPs) is an issue at both potable water and wastewater treatment plants (W/WWTPs).
What does C-DBP stand for?
The United States Environmental Protection Agency (USEPA) currently regulates two classes of carbonaceous DBPs (C-DBPs), trihalomethanes (THMs) and haloacetic acids (HAAs), under the Stage 2 Disinfection and DBP Rule.